Thanks @ferdinand, this seems to have solved my problem.
Apologies if it came across a bit abrupt, I was trying to get to the crux of it. Just seemed strange that there wasn't a way to rationally relate the zoom to any meaningful size for an orthographic camera. In other software I recall being able to set the camera as a width and height, not some factor of zoom. Made much more sense, kind of like setting it as a size. Also curious to know why they choose 1024 to underpin the zoom and not a rounded number, like 1000 (or something that can work off C4D's base unit).
But all good here - it's working now. Solved.
WP.